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991.
AlGaN/GaN metal-oxide-semiconductor (MOS) capacitor structures using atomic layer deposited high-dielectric-constant (High-k) Al2O3/La2O3 bilayer films as dielectric have been investigated using high-frequency capacitance-voltage measurement. The stable thickness and uniform surface morphology of the bilayer films with different La/Al deposition cycle ratio (La/Al ratio) were observed after rapid thermal annealing by spectroscopic ellipsometry and atomic force microscopy, respectively. We have found that with a decrease of the La/Al ratio, the dipole layer observed by X-ray photoelectron spectroscopy at Al2O3/La2O3 interfaces is close to the surface of semiconductor and the flat band voltage shifts to the negative direction. Furthermore, the dramatic drop in dielectric constant of the films as La/Al ratio decrease was caused by the formation of La(OH)3 in La2O3. Finally, the reason for the flat band voltage shifts, which is based on the dielectric constant of Al2O3 and La2O3 comprising the position of dipole layer in the dielectric films, is proposed. 相似文献
992.
《Measurement》2016
The heterogeneous nanocomposites of CuO doped TiO2 nanoparticles were synthesized using sol gel method by varying the concentration of CuO as 0.1, 0.5 and 1 mol% for the sensing of ammonia and hydrogen sulphide. The substitutional doping of CuO in TiO2 matrix was confirmed by the X-ray diffraction. Average crystallite size of the doped nanocomposites was found to reduce with increase in concentration of CuO. The 0.1 mol% CuO doped TiO2 nanocomposites showed highest sensitivity to ammonia (97%) with response time of 2 s, while 1 mol% was selective to H2S gas (77%) with response time of 45 s for 50 ppm of each gas at room temperature. 相似文献
993.
《Journal of the European Ceramic Society》2014,34(6):1537-1545
AgNb0.5Ta0.5O3 ceramics were synthesized and analyzed, with respect to their dielectric properties, in the radio- and microwave-frequency ranges. The influences of different synthesis conditions were investigated and correlated with the difficulties in preparing single-phase ceramics, as a consequence of the inhomogeneous distribution of Nb and Ta ions and the decomposition of the matrix phase. The results revealed that with the simple mixing of all three oxides and subsequent firing in air, it is possible to prepare composite material that is attractive for microwave applications due to inhomogeneity of the B-site cation distribution – a well-known issue that was in our case shown to be an advantage for decreasing the temperature dependence of the resonant frequency over a broad temperature range. On the other hand, we also succeeded in fabricating single-phase ceramics with a very high density through the initial formation of a precursor and sintering in an overpressure of oxygen. 相似文献
994.
995.
996.
Functionally graded materials are one of the most promising candidates among advanced materials. However, some challenges still exist in its fabrication methods. The current study aims to produce functionally-graded bulk Al–SiC nanocomposites by a novel multistep friction stir processing (FSP) for the first time. The SiC nanoparticles were packed into a groove on the 6061 aluminum plate and FSP was performed by using a tool with pin length of 6 mm. Subsequently, FSP was reapplied on another groove by using a tool with a shorter pin length of 3.2 mm. The desirable distribution of SiC nanoparticles in the matrix was confirmed by scanning electron and atomic force microscopes. The composition of graded sample was changed continuously from 18 to 0 wt% SiC along the thickness. Accordingly, the microhardness profile showed a maximum of 160 Hv in the enriched zone which is 3.2 times higher than the hardness of the particle-depleted zone. However, a constant hardness value of 135 Hv was obtained along the thickness of homogenous sample which is 15% lower than that of superficial layer in graded sample. Moreover, the hardness values were linearly correlated with the inverse of interparticle spacing. 相似文献
997.
《Optical Materials》2014,36(12):2201-2207
New green host materials 1-(9,9-diphenyl-9H-fluorene-2-yl)-2-phenyl-1H-benzimidazole and 1-(9,9′-spirobifluorene-2-yl)-2-phenyl-1H-benzimidazole for solution-processed green phosphorescent organic light-emitting devices have been designed and synthesized by attaching the electron transporting benzimidazole units to the rigid fluorene units. Owing to the non-planar structures, which decrease the π conjugation length of fluorene and benzimidazole rings, these fluorene derived derivatives show high triplet energy. The high triplet energy of newly host materials ensures efficient energy transfer from the host to the triplet emitter tris(2-phenylpyridine)iridium. Furthermore, the thermal, photophysical, electrochemical properties and crystal structures of 1-(9,9-diphenyl-9H-fluorene-2-yl)-2-phenyl-1H-benzimidazole and 1-(9,9′-spirobifluorene-2-yl)-2-phenyl-1H-benzimidazole were investigated. The solution-processed single-layer green device using 1-(9,9-diphenyl-9H-fluorene-2-yl)-2-phenyl-1H-benzimidazole as the host for the phosphorescence emitter tris(2-phenylpyridine)iridium showed the maximum luminance efficiencies of 10.1 cd/A. This result demonstrated that the newly synthesized, fluorene-based rigid host materials are advantageous for fabrication of highly efficient green phosphorescent organic light-emitting diodes. 相似文献
998.
A series of luminescent emission-tunable phosphors Ca8NaGd(PO4)6F2: Eu2+, Mn2+ have been prepared by a combustion-assisted synthesis method. The X-ray diffraction measurement results indicate that the crystal structure of the phosphor is a single phase of Ca8NaGd(PO4)6F2. The photoluminescence (PL) properties of Eu2+ and Mn2+-codoped Ca8NaGd(PO4)6F2 phosphors were also investigated. The phosphors can be efficiently excited by ultraviolet (UV) light and show a blue emission band at about 450 nm and a yellow emission band at about 574 nm, which originated from the Eu2+ ions and the Mn2+ ions, respectively. The efficient energy transfer from the Eu2+ ions to the Mn2+ ions was observed and its mechanism should be a resonant type via a nonradiative dipole–quadrupole interaction. A color-tunable emission in Ca8NaGd(PO4)6F2 phosphors can be realized by Eu2+ → Mn2+ energy transfer. Our results indicate that the developed phosphor may be used as a potential white emitting phosphor for UV based white LEDs. 相似文献
999.
Photopolymer are appealing materials for diffractive elements recording. Two of their properties when they are illuminated are useful for this goal: the relief surface changes and the refractive index modifications. In this paper we use a 2-dimensional model, based on direct parameter measurements, for predicting the refractive index distributions during and after illumination. We have analyzed different recording spatial frequencies for photopolymers based on PVA/Acrylamide. This model was successfully applied to different photopolymer compositions with different values of monomer diffusion and polymerization rates. 相似文献
1000.
Durable superoleophobic fabric surfaces with counterintuitive superwettability for polar solvents 下载免费PDF全文
Weijian Xu 《American Institute of Chemical Engineers》2014,60(8):2752-2756
Smart superoleophobic (SOP) cotton fabric surfaces are created only through a controlled fluorosilanization treatment, exhibiting the first‐ever extreme wetting behaviors displaying ultrarepellency to nonpolar oils and counterintuitive superwettability for all polar solvents. The smart durable SOP surfaces, demonstrated chemically, thermally, and mechanically, render great potential practical and industrial applications in robust oil shielding, effective antifouling, highly energy efficient self‐cleaning, and solely gravity‐driven oil–water separations. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2752–2756, 2014 相似文献